With this, just choose Head to Head, Headers and Volleys Match type with First to 7 Goals, and set the duration to a “ Best of 5 “ type. This one may take the longest of all of the Head to Head achievements. My suggestion is to have the second controller get possession of the ball with the goalie, and bring the ball out to about mid-pitch. There, you should be able to steal the ball, flick it up / lob it to another player and shoot the ball.
For additional Help, see “General Head to Head” under the “Head to Head Series” Achievement.