You must collect 100 titles to unlock this achievement. Collecting 100 titles will come naturally as you are unlocking other achievements, specifically Waiting for the Trade and Master of Tasks. There are a variety of titles and can be unlocked in various ways. Each individual character has a title for the following things:
- Clear Arcade mode with ____ on any difficulty
- Clear Arcade mode with ____ on Hard
- Complete five missions with ____
- Complete all missions with ____
- Use ____ 30 times.
- Use ____ 100 times.
There are 48 characters in the Ultimate Marvel vs Capcom 3 cast as well as the 2 additional DLC characters Jill and Shuma, completing all the endings with each character for Waiting for the Trade will already qualify you for 48/100 titles for this achievement. If you have extra DLC characters 50/100. While completing missions for Master of Tasks you should be able to unlock the title for completing five missions with each character giving you your 100 titles if you were to complete the 5 missions with each character, if this is too difficult for you here are your other options for titles.
Unlockable Online Titles
There are 21 titles for winning matches online starting at 1 online win to 1000. If you are looking to obtain the 1000 for Ultimate you will have to win 100 ranked Matches regardless for Fighting Machine and then you have to participate in 300 matches online anyway for Forged from Steel. Lastly, the 100 wins will not be enough to raise you to a 6th rank for any class for your Mega Good trophy so you will have to continue playing regardless. You may not get all the way to 1000 but its nice to know you’ll still be unlocking titles while grinding out your online achievements. Alternatively you could also boost these if you wish.
Player Point Titles
These titles should already been unlocked as you are working on your Player Points for Divine Brawler. There are 33 titles in total for this category which ends with 999,999 player points unlock so by the time you have your trophy for the play points you should also have 14 of these titles and then whatever else you unlock grinding out other trophies after it. Refer to Divine Brawler for more information in regards to Player Points.
There are various miscellaneous titles as well. You can check the unlock conditions for them under your titles by pressing .